wsanders,
Have a read of the best practices guide:
http://www.hpcfactor.com/support/cesd/h/0015.asp
It coves the basic should and should nots when storing batteries.
The Coin Cell is designed for one thing and one thing only; vRAM integrity conservation.
When the main cell is out of the device, everything else in it except the main RAM and RTC
(Real Time Clock
) is shut off from the circuit. In this state the device cannot start up at all unless AC is applied, or the battery replaced.
The main purpose of the Coin Cell being there, however, was for when you discharge the main cell too heavily. The Coin Cell provides the current against whatever reserves are left in the depleted main cell to keep the devices RAM powered. In this state with a healthy main cell you can keep a device doing for upto 'weeks'.
As Snappy! said above, when on its own the 3v cell
(remember it's a 12v device
) is just sucked into the system at a steady rate of knots.
By constantly using it on the mains, that is the fastest way to kill any battery. While Lithium Ion cells do have better charge circuits in them, preventing over chargin, they still shouldn't be perpetually on mains. The best thing you can do with a battery device is use it
(and read the guide
).